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Multiplicity and stability of CSTR-Separator-Recycle Systems

机译:CSTR-分离器-循环系统的多样性和稳定性

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摘要

The nonlinear behaviour of several CSTR-Separator-Recycle systems is studied by rigorous application of the singularity theory. The plant Damkohler number (Da) is introduced as a parameter of the dimensionless balance equations. A feasible operating point exist iff Da > Da~(cr), where the critical value Da~(cr) corresponds to a singular point of the model equations. For one-reactant n th-order isothermal reaction, the feasible operating point is unique and stable. In other cases (second-order isothermal reaction involving two reactants; first-order adiabatic reaction), multiple steady states exist, the range of achievable conversion being limited by the instability of the low-conversion state.
机译:通过严格应用奇点理论研究了几种CSTR-Separator-Recycle系统的非线性行为。引入设备的Damkohler数(Da)作为无量纲平衡方程的参数。当Da> Da〜(cr)时,存在一个可行的工作点,其中临界值Da〜(cr)对应于模型方程的奇点。对于一个反应物的n阶等温反应,可行的工作点是唯一且稳定的。在其他情况下(涉及两种反应物的二阶等温反应;一阶绝热反应),存在多个稳态,可实现的转化范围受到低转化率状态的不稳定性的限制。

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