首页> 外文会议>2012 AIChE spring meeting amp; 8th global congress on process safety. >Natural Gas to Ethylene in One Step Siluria Technologies OCM (Oxidative Coupling of Methane)
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Natural Gas to Ethylene in One Step Siluria Technologies OCM (Oxidative Coupling of Methane)

机译:天然气一步一步转化为乙烯Siluria Technologies OCM(甲烷的氧化偶联)

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The oxidative coupling reaction of methane for direct, one-steprnconversion of C1’s to C2’s has been known for many years but neverrncommercialized. Siluria Technologies has succeeded by bringing together 3 majorrnscientific advances of the past decade that were unavailable to earlierrnresearchers in this chemistry. The advances are (1) Biomaterial Templating - thernuse of genetically engineered biomaterials to influence the structure of inorganicrncatalysts grown on these templates, (2) Nanowire Catalyst Design - a syntheticrnmethod that permits the influencing of catalyst properties by changing the activernsites, and which can be made under commercially scalable synthetic conditions,rnand (3) High-throughput Screening – that allows for measuring gas-to-gasrnreactions orders of magnitude faster than in traditional reactors.rnIn addition, all of Siluria's R&D and experimental work on the reaction hasrnbeen limited to commercially viable process conditions and reactorrnconfigurations. Work in the 1980’s and early 1990’s on this highly exothermicrnreaction, typically using catalysts produced by conventional bulk methods, wasrnlimited to temperatures, pressures, or other process conditions that were outsidernof the practical engineering window for a commercial system.rnThe recent and rapid pace of natural gas discovery and development inrnNorth America and other regions provides a very strong business case for therndeployment of this technology.
机译:甲烷用于将C1直接一步转化为C2的氧化偶联反应已为人所知,但从未商业化。 Siluria Technologies成功地整合了过去十年中在该化学领域早期研究人员无法获得的3项重大科学进展。取得的进展是(1)生物材料模板化​​-利用基因工程生物材料来影响在这些模板上生长的无机催化剂的结构,(2)纳米线催化剂设计-一种合成方法,可通过改变活性位点来影响催化剂的性能,并且可以(3)高通量筛选–与传统反应器相比,测量气对气反应的速度要快几个数量级。此外,Silurua在反应方面的所有研发和实验工作都限于商业上可行的工艺条件和反应器配置。在1980年代和1990年代初,通常使用通过常规本体方法生产的催化剂进行这种高度放热的反应,将其限制在温度,压力或其他工艺条件之外,这些条件超出了商业系统的实际工程窗口范围。北美和其他地区的天然气发现与开发为该技术的部署提供了非常有力的商业案例。

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