COLLOIDAL SYSTEMS CONTAINING FREE RADICAL-FORMING PARTICLES AND COMPOSITES ON THEIR BASIS

摘要

Controlled surface activity and reactivity of new carbon-chain functional surface-active oligoperoxides (FSAP) and derived metal complexes (OMC) with side and end di-tertiary and tert-alkyl (aryl) peroxidic, respectively, and other active functional groups caus'e the possibility of their tailored utilization as emulsifiers, surface-active initiators and modifiers of the phase boundaries of liquid, solid and mixed phases in different colloidal systems in a wide temperature range. New materials can be developed such as water and hydrocarbon polymer dispersions, artificial water dispersions of unsaturated polyesters and alkyd resins, polymer/polymeric blends, active glass and carbon fibers, dispersed fillers, reinforced and filled polymer composites with the definite special properties. Methods for the obtaining and the application of these materials are described.