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The Effects of Medium in Nitric Acid ― Tributylphosphate Complex Formation

机译:硝酸对磷酸三丁酯络合物形成的影响

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摘要

An influence of the effects of medium on the constants of formation of various complexes of nitric acid in organic phase at the extraction with undiluted TBP has been studied. The effects of medium were shown to be rather small in a whole due to mutual compensation of the variations of activity coefficients of TBP and extracting complexes along the extraction isotherm. Similar compensation takes place under a dilution of TBP with kerosene. The compensation was attributed to general regularities of molecular solvation.
机译:研究了在未稀释的TBP萃取条件下,介质对有机相中各种硝酸络合物形成常数的影响。由于对TBP活度系数的变化和沿提取等温线提取复合物的相互补偿,介质整体上的影响很小。在用煤油稀释TBP的情况下也会发生类似的补偿。补偿归因于分子溶剂化的一般规律。

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