METHOD FOR OBTAINING CORROSION INHIBITORS BASED ON TETRAPROPYLENE PENTAMINES FOR OILFIELD, MINERALIZED AND HYDROGEN SULFIDE-CONTAINING MEDIA

摘要

FIELD: oil and gas industry. ;SUBSTANCE: invention relates to the field of protection of gas and oil field equipment and pipelines operating in highly mineralized hydrogen sulfide-containing aqueous media from corrosion, as well as transportation of oil and gas. A method for producing corrosion inhibitors for oilfield, mineralized and hydrogen sulfide-containing media based on polypropylene polyamines and carboxylic acids with distillation of reaction water and impurities is characterized by the fact that, as polypropylene polyamine, tetrapropylenepentamine [(3,6,9,12-tetramethyl)-1,4,7,10,13-pentamino-tridecane] is used, which reacts with monocarboxylic acid first at a temperature of 160°С for 4-5.5 hours, then at a temperature of 255-260°С for 2-2.5h in a molar ratio of tetrapropylenepentamine : monocarboxylic acid equal to 1 : 2-2.1, followed by the interaction of the obtained bis-imidazolines with acrylic acid nitrile at a temperature of 80°С in molar ratio of bis-imidazoline based on tetrapropylenepentamine : acrylic acid nitrile, equal to 1:1.05.;EFFECT: invention expands the resource base and the range of products, reduces the price of the target product.;1 cl, 1 tbl, 2 ex