Analysis of electrochemical impedance spectra using phase angle symmetry across log frequency

摘要

A method is disclosed for analysis of the impedance behavior of electrochemical impedance circuits or the Transfer Function for input-output systems, utilizing the symmetry of the phase angle response with the Log of the frequency to allow for determination of the lower frequency half of the impedance response over Log frequency based only on information from the upper half response. The underlying analytical basis for the symmetry of the phase angle and the methods for applying this analysis are applicable to simple R-C circuits, Randle circuits, Constant Phase Element (CPE)-Randles and coating model circuits. Symmetric functions describing the derivative of the phase angle, θ, with respect to the Log of the frequency can be used to determine the circuit elements requiring only the high frequency information. Only knowledge of the high frequency-based response is needed to know how the low frequency range behaves. Capturing high frequency impedance can be done in a few seconds compared with many hours of experimental effort to obtain low frequency behavior, to allow for continuous monitoring of polarization resistance with only a few seconds of data capture required. The method is applicable to numerous sensor applications across a range of disciplines including corrosion focused industries, battery technology and bioelectrochemical fields, and applicable to other Transfer Function analyses that include such as dielectric relaxation and complex modulus.