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PROCESS FOR TREATING A MIXED FEED OF HYDROGEN SULFIDE GAS AND AMMONIA GAS TO PRODUCE AMMONIUM THIOSULFATE AND INCLUDING METHODOLOGY FOR EMISSIONS CONTROL
PROCESS FOR TREATING A MIXED FEED OF HYDROGEN SULFIDE GAS AND AMMONIA GAS TO PRODUCE AMMONIUM THIOSULFATE AND INCLUDING METHODOLOGY FOR EMISSIONS CONTROL
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机译:处理硫化氢气体和氨气的混合饲料的方法,以产生硫代硫酸铵,包括排放控制方法
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摘要
This invention relates to production of an aqueous solution containing ammonium thiosulfate from a feed gas containing hydrogen sulfide (H2S) and ammonia (NH3). Sufficient separation of feed gas H2S from NH3 is achieved by controlling individual NH3 and H2S absorption mass-transfer rates in a single co-current stage, whereby a first gas contacts a first liquid containing ammonium bisulfite (ABS). Substantially more NH3 is absorbed than H2S, converting ABS to diammonium sulfite (DAS). A portion of DAS reacts with a sufficiently small portion of H2S to produce ATS and leaves as a second liquid stream. A larger portion of H2S leaves as a second gas stream. The second gas stream is oxidized to sulfur dioxide (SO2) comprising a third gas stream. The third gas stream contacts the second aqueous stream in a second contact stage whereby DAS in the second liquid stream is converted to ABS and returned to the first contacting zone.
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