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CATALYST FOR LOW-TEMPERATURE PLASMA CATALYTIC CONVERSION OF GASEOUS ALKANE AND PREPARATION METHOD THEREFOR

机译:气态烷烃低温等离子体催化转化催化剂及其制备方法

摘要

A catalyst for the low-temperature plasma catalytic conversion of a gaseous alkane and a preparation method therefor. The catalyst is composed of a metal having an active site and a matrix material that provides an acidic site and a porous structure, the matrix material being a molecular sieve (HZSM-5, UZSM-5), an oxide (SiO2, Al2O3, TiO2, and ZrO2), a sulfide (MoS2), activated carbon, and carbon nitride (C3N4). The metal having an active site is one among or a mixture of multiple Ag, Pt, Pd, Ga, Zn and Ti, and the load of each metal on the matrix material is 0.1-10% of the mass of the matrix material. The catalyst prepared may achieve at low temperature and normal pressure the low-temperature plasma catalytic conversion of a gaseous alkane (a C1-C5 monomer or a mixture of two or more) into a liquid alkane (a C6-C12 alkane containing a branched chain) or a chemical having a high added value, and simultaneously produces less coke.
机译:气态烷烃低温等离子体催化转化率及其制备方法催化剂。催化剂由具有活性部位的金属和提供酸性位点和多孔结构的基质材料组成,基质材料是分子筛(HZSM-5,UZSM-5),氧化物(SiO 2 ,Al 2 O 3 ,tio 2 ,zro 2 ),硫化物(mos <亚> 2 ),活性炭和氮化碳(C 3 n 4 )。具有活性位点的金属是多个Ag,Pt,Pd,Ga,Zn和Ti的混合物中的一种,Zn和Ti的混合物,并且基质材料上的每个金属的负载是基质材料质量的0.1-10%。制备的催化剂可以在低温和正常压力下达到气态烷烃(C1-C5单体或两种或多种混合物)的低温等压催化转化为液态烷烃(含有支链的C6-C12烷烃)或具有高附加值的化学物质,同时产生较少的焦炭。

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