POLYURETHANE COMPOSITES COMPRISING NANOCRYSTALLINE CELLULOSE AND METHOD FOR IMPROVING PROPERTIES OF POLYURETHANES THEREOF

摘要

A process for preparing polyurethane composites includes (i) providing a dispersion of nanocrystalline cellulose in (a) one or more polyols, (b) one or more isocyanates, or (c) one or more polyols and one or more isocyanate, mixed together; wherein the amount of water in the nanocrystalline cellulose is less than about 1% w/w; (ii) mixing the dispersion of (i)(a) with an isocyanate or (i)(b) with a polyol and a catalyst to allow polymerization; or mixing the dispersion of (i)(c) and a catalyst to allow polymerization; and (iii) isolating the polyurethane composite. A method for improving properties of polyurethanes includes dispersing nanocrystalline cellulose into one or both parts of a two part polyol/isocyanate precursors prior to allowing polymerization of the precursors, wherein the amount of water in the nanocrystalline cellulose is less than about 1% w/w; mixing the dispersion with a catalyst; and polymerizing the precursors to provide the polyurethane.