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REDOX REVERSIBLE FLUORESCENT PROBE AND PERFORMING SINGLE-ELECTRON TRANSFER FLUORESCENCE PROBING

机译:氧化还原可逆荧光探针和执行单电子转移荧光探测

摘要

A redox reversible fluorescent probe for performing single-electron transfer fluorescence probing includes: a redox moiety including: a terminal moiety; an electron transfer metal coordinatively bonded to the terminal moiety; and a bridge moiety coordinatively bonded to the electron transfer metal; and a fluorescent moiety covalently bonded to the bridge moiety of the redox moiety and comprising: an electron bandgap mediator that is covalently bonded to the bridge moiety; a coordinate center covalently bonded to the electron bandgap mediator and that forms a Zwitterionic member with an atom in the electron bandgap mediator; and a steric hinder bonded to the electron bandgap mediator to provide steric hindrance for protection of the coordinate center.
机译:用于进行单电子转移荧光探测的氧化还原可逆荧光探针包括:氧化还原部分,包括:末端部分;电子转移金属与末端部分合粘合;和桥部与电子转移金属相同地键合;和与氧化还原部分的桥接部分共价键合的荧光部分,并包含:电子带隙介体,其与桥部分共价键合;与电子带隙介体共价键合的坐标中心,并且在电子带隙介质中形成具有原子的两性离子构件;并且粘合到电子带隙介体的空间阻碍,以提供用于保护坐标中心的空间阻碍。

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