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CATALYST FOR CARBONYLATION OF DIMETHYL ETHER TO PRODUCE METHYL ACETATE, PREPARATION METHOD THEREFOR, AND USE THEREOF

机译:二甲醚羰基化催化剂制备乙酸甲酯,其制备方法及其用途

摘要

Disclosed are a catalyst for the carbonylation of dimethyl ether to produce methyl acetate, a preparation method therefor, and the use thereof. The catalyst contains a modified H-MOR molecular sieve, wherein the modified H-MOR molecular sieve is prepared by means of the exchange of an H-MOR molecular sieve with a pyridinium salt. Methyl acetate is produced by passing dimethyl ether and a raw material gas containing carbon monoxide through a reactor charged with an acidic molecular sieve catalyst which selectively regulates active sites, and performing a reaction under the conditions of a reaction temperature of 150-280°C, a reaction pressure of 0.5-25.0 MPa, and a space velocity of dimethyl ether of 0.2-4 h -1.
机译:公开了一种用于产生二甲醚的羰基化的催化剂,以产生乙酸甲酯,其制备方法及其用途。催化剂含有改性的H-MOL分子筛,其中通过用吡啶鎓盐的H-Mor分子筛的交换制备改性的H-Mor分子筛。通过将二甲醚和含有一氧化碳的原料气体通过加入的酸性分子筛催化剂的反应器通过,通过选择性地调节活性位点,并在反应温度为150-280℃的条件下进行反应来制备甲基乙酸酯。反应压力为0.5-25.0MPa,与0.2-4小时的二甲醚的空速,为0.2-4小时-1 -1 -1 / sop>。

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