The present invention provides a material having a thermochromic effect and a preparation method therefor, and a thermochromic smart window. The method comprises the following steps: carrying out a hydrothermal reaction on raw materials vanadyl sulfate and ammonium tungstate to obtain V 1-xW xO 2 powder; dispersing the V 1-xW xO 2 powder in a solvent, and adding a reactive monomer and a dispersant to carry out hydrolysis and condensation reactions under the action of a catalyst to obtain V 1-xW xO 2@SiO 2 composite powder; and enabling an emulsion polymerization reaction of the V 1-xW xO 2@SiO 2 composite powder and N-isopropylacrylamide in nitrogen and heating conditions under the action of a cross-linking agent and an initiator to obtain a V 1-xW xO 2@SiO 2/PNIPAM composite solution. The material of the present invention has the advantages of high visible light transmittance, high variable temperature spectrum regulation efficiency, high photo-thermal stability, high adaptability, etc.
展开▼
机译:本发明提供了一种具有热致变色效果的材料和其制备方法和热致变色智能窗口。该方法包括以下步骤:在原料制备硫酸盐和钨酸盐上进行水热反应,得到v 1-x sub> w x sub> O 2 sub >粉末;将V 1-x / sub> w x / sub> O 2℃,并加入反应性单体和分散剂以进行水解和冷凝剂在催化剂的作用下得到v 1-x / sub> w x / sub> O 2 sub> @sio 2 sub>复合粉末; v 1-x / sub> w x / sub> O 2 sub> @sio 2 sub>复合粉末的乳液聚合反应在交联剂和引发剂的作用下在氮气中的氮和加热条件下的N-异丙基丙烯酰胺,得到V 1-x / sub> w x sub> O 2 子> @sio 2 sub> / pnipam复合解决方案。本发明的材料具有高可见光透射率,高可变温度谱调节效率,高光稳定性,高适应性等的优点。
展开▼