embedded image wheren is an integer equal to 0, 1 or 2,R1 and R2 are H or an aliphatic hydrocarbon group,one of R3 and R4 has the following formula (II):; embedded image where R5 and R6 are a hydrocarbon, hydroxyl or alkoxyl group, and the other one of R3 and R4 has one of the following formulas (II′) and (III): ; embedded image where R5′ and R6′ are a hydrocarbon, hydroxyl or alkoxyl group, and R7 and R8 are H or an aliphatic hydrocarbon group. ;The invention also relates to a method for recovering at least one rare earth using said compound, as well as to specific compounds as such."/> Use of novel compounds for selectively extracting rare earths from aqueous solutions including phosphoric acid and associated extraction method
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Use of novel compounds for selectively extracting rare earths from aqueous solutions including phosphoric acid and associated extraction method

机译:使用新化合物从包含磷酸和相关提取方法的水溶液中选择性地提取稀土化合物

摘要

The invention relates to the use, as an extraction agent for extracting at least one rare earth from an aqueous phase including phosphoric acid, of at least one compound of the following general formula (I):; embedded image wheren is an integer equal to 0, 1 or 2,R1 and R2 are H or an aliphatic hydrocarbon group,one of R3 and R4 has the following formula (II):; embedded image where R5 and R6 are a hydrocarbon, hydroxyl or alkoxyl group, and the other one of R3 and R4 has one of the following formulas (II′) and (III): ; embedded image where R5′ and R6′ are a hydrocarbon, hydroxyl or alkoxyl group, and R7 and R8 are H or an aliphatic hydrocarbon group. ;The invention also relates to a method for recovering at least one rare earth using said compound, as well as to specific compounds as such.
机译:本发明涉及用途,作为用于从包含磷酸的水相中萃取至少一种稀土的提取剂,其中至少一种通式(I)化合物: <化学ID =“Chem-US-00001”> “嵌入式图像”文件=“US10934604-20210302-C00001.gif”他=“19.30mm”imgContent 在哪里 n是一个等于0,1或2的整数, R 1 和r 2 是h或脂族烃类, R 3 和R 4之一具有以下公式(ii): ; <化学ID =“Chem-US-00002”> “嵌入式图像”文件=“US10934604-20210302-C00002.gif”他=“16.59mm”imgContent 其中R 5 和R 6 是烃,羟基或烷氧基,和 R 3 和R 4 中的另一个具有以下公式(II')和( iii): ; <化学ID =“Chem-US-00003”> “嵌入图像”文件=“US10934604-20210302-C00003.gif”他=“49.78mm”ImgContent 其中R 5 '和R 6 '是烃,羟基或烷氧基,和R 7 和R 8 是h或脂族烃类。 ;本发明还涉及使用所述化合物回收至少一种稀土的方法,以及如此。

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