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Method for producing silicone polymer

机译:生产硅氧烷聚合物的方法

摘要

PROBLEM TO BE SOLVED: To provide a method for producing a silicone polymer which is liquid at room temperature, has little absorption of ultraviolet rays, is transparent, and has excellent ultraviolet curability. SOLUTION: Compounds 88 to represented by the general formula (1) R1Si (OR2) 3 ... (1) (in the formula, R1 represents a 3-methacryloxypropyl group and R2 represents a hydrocarbon group). 92 mol% and 8 to 12 mol% of the compound represented by the general formula (2) R3Si (OR4) 3 ... (2) (in the formula, R3 represents a methyl group and R4 represents a hydrocarbon group). In the presence of tetramethylammonium hydroxide, isopropyl alcohol was added 0.5 to 1.5 times by weight and methyl isobutyl ketone was added 2.0 to 3.0 times by weight based on the total amount of the silane compound. , 2.5 to 3.3 mol times of water is added and reacted. A silicone polymer having a weight average molecular weight of 2000 to 2600, a silanol group at the end, and a liquid at 5 to 40 ° C. Manufacturing method. [Selection diagram] None
机译:要解决的问题:提供一种用于在室温下产生液体的硅氧烷聚合物的方法,紫外线的吸收较小,是透明的,具有优异的紫外线固化性。溶液:由通式(1)R 1 Si(OR 2)3 ...(1)表示的化合物88(在式中,R1表示3-甲基丙烯酰氧基丙基,R 2代表烃基)。由通式(2)R3SI(OR 4)3 ...(2)表示的92mol%和8至12mol%的化合物(在式,R 3表示甲基,R4代表烃基)。在氢氧化四甲基铵的存在下,加入异丙醇0.5至1.5倍,基于硅烷化合物的总量加入2.0至3.0倍的甲基异丁基酮。 ,加入2.5至3.3摩尔水的水并反应。硅氧烷聚合物的重均分子量为2000至2600,末端的硅烷醇基,液体为5-40℃。制造方法。 [选择图]无

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