Interpolymers of mono-2-alkenyl ethers of saturated monohydric alcohols or phenols with esters of saturated monohydric alcohols or phenols and alpha-unsat-urated aliphatic carboxylic acids

摘要

Saturated copolymers are prepared by heating together at a temperature of 25 DEG to 120 DEG C. a monoethylenic 2-alkenyl ether and a monoethylenic ester of an alpha ethylenic carboxylic acid in the presence of a peroxidic catalyst. Ethers specified are allyl methyl, methallyl ethyl, chlorallyl ethyl, methallyl methyl, methallyl benzyl, and allyl butyl ethers; esters specified are methyl and phenyl acrylates, methyl methacrylate, ethyl chloroacrylate, diethyl fumarate, dimethyl maleate, dimethyl and dihexyl itaconates, and the methyl and other alkyl esters of chloromaleic, citraconic, mesaconic, and aconitic acids. Peroxidic catalysts specified are hydrogen, acetyl, lauroyl, and succinyl peroxides, tert.-butyl hydroperoxide, peroxycarbonates, peroxyborates, and peroxysulphates. Copolymerization may be carried out in the presence or absence of solvents, diluents, emulsifying agents, and polymerization regulators such as methallyl chloride; the copolymers may be precipitated from solution with non-solvents, such as n-hexane, or from aqueous emulsion with electrolytes, and purified by extraction with solvents, and drying. The products may be used as adhesives, for waterproofing, for the preparation of rods, blocks, sheets, films and tubes, and, in solution, as lacquers. The copolymers may be after-treated by alcohol interchange with 2-alkenyl alcohols such as allyl, methallyl, ethallyl, 2-chloroallyl and crotyl alcohols by dissolving the copolymer in the 2-alkenyl alcohol and heating in the presence of an esterification catalyst such as sodium hydroxide or p-toluenesulphonic acid, and optionally a polymerization inhibitor such as copper or hydroquinone; the product is purified by dissolving it in a solvent such as acetone, and precipitating it with a non-solvent such as n-hexane. The products of this reaction may be converted to the insoluble, infusible state by heating in the presence of polymerization catalysts, or may be further copolymerized with monomers such as vinyl acetate, methyl acrylate, methyl and allyl methacrylates, diethyl and diallyl fumarates, and diallyl phthalate, producing copolymers which may be converted to the infusible state with the aid of heat and polymerization catalysts, such as benzoyl peroxide.