ph meter with temperature compensated large range scale and small range expanded scale

摘要

888,919. Electrolytic testing apparatus. MARCONI INSTRUMENTS Ltd. July 21, 1960 [Dec. 18, 1959], No. 43069/59. Class 37. In a pH meter including full temperature compensation (both slope and initial) and provision for switching from a wide range end zero meter to an expanded-scale, narrowrange, centre-zero meter, the scale changing means is arranged to alter the compensation to make it appropriate to the range being employed and the narrow-range is made adjustable so that its centre zero can occupy any point or one of a selected number of points in the pH scale. The potential on the glass electrode G is applied to a differential amplifier arrangement comprising valves 2, 3 and 4, the output at the anode 20 of valve 4 being dependent on the difference between the inputs on the grids 1 and 5. A further amplifier 6, with a millivoltmeter 8 from which the pH may be read, forms part of a feed-back circuit to grid 5. The ranges are selected by switches A, B included in in various parts of the circuit, contacts CS6 changing the range, contacts CS1 and CS2 determining the slope of the compensation effected by thermistor T1, and contacts CS3-CS6 determining the initial compensation by the thermistor T2. The position of the range in the pH scale is determined by variable resistors 33, 32, providing coarse and fine control respectively, and the variation drive of resistor 32 is ganged to that of a variable resistor 28 in the temperature compensation network. The resistor 30 included in the A position serves to transfer the zero from the centre scale position to the B range, and resistor 26 provides for an adjustment to suit the iso-potential point of any particular glass electrode in use. Switch S and power source 29 are provided for calibration purposes.