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Improvements in the treatment of cotton, linen and rayon fabrics

机译:改善棉,亚麻和人造丝织物的处理

摘要

The wet and dry crease recovery properties of a fabric consisting wholly or partly of cotton linen or viscose rayon are improved by (1) impregnating the fabric with 50-150% by weight of an aqueous solution containing at least one nitrogenous cellulose reactant resin and an acid suitably buffered so that the solution has a pH of 0.5-3. (2) partially drying it to a residual moisture content of above 6% by weight, (3) holding it in a smooth crease-free condition for at least 2 hours at a temperature of 10 DEG -50 DEG C during which time reaction takes place while the fibres are still in a swollen state, (4) heating it at 90 DEG -150 DEG C. for 1-5 minutes either with or without intermediate drying, (5) washing it in aqueous alkali e.g. sodium carbonate and then water to remove the acid and any unreacted material and (6) drying it. The nitrogenous cellulose reactant resin may be dimethylol cyclicethylene urea, dimethylol-1, 3-propylene urea, dimethylol dihydroxyethylene urea, dimethylol 4-methoxy, 5-dimethyl propylene urea, dimethylol hydroxy propylene urea or dimethylol methoxyethyl carbamate. Suitable buffer systems are mixtures of sulphuric acid and sodium dihydrogen phosphate, hydrochloric acid and sodium acetate, citric acid and disodium hydrogen phosphate. The treating solution may also contain a polyethylene emulsion softener. After partial drying the fabric may be wound on to a mandrel to form a roll and covered with a polyethylene sheet to prevent drying of the fabric during the lying period.
机译:全部或部分由棉亚麻纤维或粘胶人造丝组成的织物的湿和干折痕恢复性能可通过以下方法得到改善:(1)用50-150%(重量)的含至少一种含氮纤维素反应物树脂和一种水溶液的水溶液浸渍该织物。适当缓冲酸,使溶液的pH值为0.5-3。 (2)将其部分干燥至残留水分含量高于6重量%,(3)在10℃-50℃的温度下将其保持在光滑无皱纹的条件下至少2小时,在此期间反应将其放置在纤维仍处于溶胀状态时,(4)在有或没有中间干燥的情况下将其在90°-150°C加热1-5分钟,(5)在碱水溶液中洗涤,例如碳酸钠,然后加水去除酸和所有未反应的物质,然后将其干燥(6)。含氮纤维素反应物树脂可以是二羟甲基环亚乙基脲,二羟甲基-1、3-丙烯脲,二羟甲基二羟基乙烯脲,二羟甲基4-甲氧基,5-二甲基丙烯脲,二羟甲基羟基丙烯脲或二羟甲基甲氧基乙基氨基甲酸酯。合适的缓冲系统是硫酸和磷酸二氢钠,盐酸和乙酸钠,柠檬酸和磷酸氢二钠的混合物。处理溶液还可包含聚乙烯乳液柔软剂。在部分干燥之后,可以将织物缠绕到心轴上以形成卷,并用聚乙烯片材覆盖以防止在躺卧期间织物干燥。

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