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Solid solutions of phosphorsaeurederivaten in resins, in particular for construction and domestic purposes, and method for their preparation

机译:磷酰胺中的磷酸酯类固溶体的固溶体,特别是用于建筑和家庭用途的固溶体及其制备方法

摘要

A solid pesticidal composition, particularly suitable for application on walls, ceilings, floors or other absorbent surfaces, comprises a pesticidal agent and a fusible water-insolubilisation resin compatible therewith, the pesticidal agent having the general formula FORM:1070026/A5-A6/1 in which R and R1 are the same or different and each is a saturated linear- or branched-chain alkyl radical having from 1 to 4 carbon atoms and R2 is hydrogen or a linear- or branched-chain alkyl radical having from 1 to 4 carbon atoms. Suitable resins include hpenolic, terpenic, terpene phenolic, cumaronic and cumarone indenic resins, and modified colophonium having a softening point of from 80 to 120 DEG C. The composition may also contain fillers (e.g. diatomaceous earth, talc, clay or bentonite) and surface active agents (e.g. alkali metal or alkaline earth metal arylakyl-sulphonates and condensation products of ethylene oxide with fatty acids or alkylphenols). In the examples, the pesticidal agent employed is the amide, monomethylamide, monoethylamide or monoisopropylamide of O,O-diemthyl-dithiophosphorylacetic acid. In some examples, the composition also contains the O,O-diethyl-dithiophosphoric ester of 3,4-tetramethylene rembelliferone. Tests are described which show the efficiency of some of the compositions of the invention in killing flies.
机译:固体农药组合物,特别适合在墙壁,天花板,地板或其他吸收性表面上施用,包含农药和与其相容的易熔的不溶于水的树脂,该农药具有通式其中R和R 1相同或不同,并且每个是具有1至4个碳原子的饱和直链或支链烷基,并且R 2是氢或具有1至4个碳原子的直链或支链烷基4个碳原子。合适的树脂包括庚二烯,萜烯,萜烯酚醛,枯烯和古马隆树脂,以及软化点为80-120℃的改性树脂。该组合物还可以包含填料(例如硅藻土,滑石,粘土或膨润土)和表面活性剂(例如碱金属或碱土金属芳基烷基磺酸盐,以及环氧乙烷与脂肪酸或烷基酚的缩合产物)。在实施例中,使用的农药是O,O-二甲基-二硫代磷酸乳酸的酰胺,单甲基酰胺,单乙基酰胺或单异丙基酰胺。在一些实例中,该组合物还包含3,4-四亚甲基瑞贝弗隆的O,O-二乙基-二硫代磷酸酯。描述了测试,该测试显示了本发明的某些组合物在杀死果蝇中的效率。

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