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THERMALLY STABLE ETHYLENE POLYMERS.

机译:热稳定的乙烯聚合物。

摘要

Thermostable ethylenic polymers contng. substd. phosphites and phenols. Olefinic polymer cpds. contain a major proportion of an ethylenic polymer chosen from low density polyethylene, copolymers of ethylene with 2-25% of (meth)acrylic acid or their alkali metal or alkaline earth metal salts, or copolymers of ethylene and acrylates of alkyls with 1-18C, and a proportion of 0.005 to 5% of a mixture of 1.5-9 pts. of 2,6-bis(2'-hydroxy-3'-t-butyl-5'-methylbenzyl)-4-methyl-phenol and of 1 pt. of an alkyl substd. phenyl phosphite chosen from monophosphites of formula: in which n is 1, 2 or 3; R is an alkyl radical of 9-12C atoms, and diphosphates of formula: in which (A) is a bivalent radical from -O(CH2.CH2.O)y -O(CH2CHO)y, -O(CH2)xO-, -OCH2.CHO- or -O(CH2)zS(CH2)zO-, in which x is 2-10, y is 2-6 and z is 2-5.
机译:耐高温的烯类聚合物。取代亚磷酸酯和酚。烯烃聚合物cpds。包含大部分选自低密度聚乙烯的乙烯类聚合物,乙烯与2-25%的(甲基)丙烯酸或其碱金属或碱土金属盐的共聚物,或乙烯与1-18C的烷基丙烯酸酯的共聚物和1.5-9 pts的混合物的0.005至5%的比例。 2,6-双(2'-羟基-3'-叔丁基-5'-甲基苄基)-4-甲基苯酚和1 pt。烷基取代基亚磷酸苯基酯选自式:其中n为1、2或3; R是9-12C原子的烷基,和下式的二磷酸酯:其中(A)是-O(CH2.CH2.O)y-O(CH2CHO)y,-O(CH2)xO-的二价基团。 ,-OCH 2 .CHO-或-O(CH 2)z S(CH 2)z O-,其中x是2-10,y是2-6并且z是2-5。

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