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process for selective removal of nickel from a copper and nickel containing oximloesung
process for selective removal of nickel from a copper and nickel containing oximloesung
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机译:从含铜和含镍的肟橡胶中选择性去除镍的方法
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摘要
The present invention relates to an acid stripping process for recovering nickel selectively from an organic oxime containing copper and nickel. By employing only limited amounts of acid, sufficient to provide about equivalent latent hydrogen ion therein to latent nickel ion of the oxime stream, nickel can be stripped in a multistage countercurrent process preferentially to copper. Hydrogen ion of the acid exchanges with nickel ion of the oxime molecule in accordance with the equation: (R2 DEG Ni)org. + 2(H+)aqu.-(2R DEG H)org. + (Ni++)aqu.
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机译:本发明涉及一种用于从含有铜和镍的有机肟中选择性地回收镍的酸汽提方法。通过仅使用有限量的酸,该酸足以在其中提供与肟物流的潜在镍离子约等价的潜在氢离子,可以在多级逆流工艺中优先于铜汽提镍。酸的氢离子与肟分子的镍离子交换,其方程式为:(R2 DEG Ni)org。 +2(H +)水->(2R DE H)org。 +(Ni ++)水。
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