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Self lubricating PTFE based compsn. - contg. polyamino bis-maleimide resin prepolymer

机译:自润滑PTFE基复合材料。 -续聚氨基双马来酰亚胺树脂预聚物

摘要

Compsn. comprises (1) 20-85 wt. % of a polyaminobisimide resin prepolymer and (2) a solid lubricant comprising 25-80 PTFE, or 15-80% CFx where x is 0.85-1, or 25-80% of a mixt. of PTFE and molybdenum bisulphide or CFx the amt. of (2) being based on the total wt. of resin and solid lubricant in the finished article after hardening of the resin. Used for prodn. of components operating at high speed or high temps., e.g. ball bearing race, gears, goumals etc. Pref. the prepolymer as prepd. by heating at 150-250 degrees C a cpd. of formula (I) (where D is a divalent gp. contg. a C-C double bond., and A is =2 C divalent gp) with a diamine H2N-B-NH2 (II), (where B is is not 30C divalent gp.). (I) is pref. N,N'-4,4'-diphenylmethanebis malei-mide and (II) is pref. bis (4-amino phenyl) methane. The lubricant pref. comprises 30-50 wt. % PTFE or 15-30% CFx, or 28-32% PTFE and 3-6% MoS2.
机译:Compsn。包括(1)20-85 wt。 %的聚氨基双酰亚胺树脂预聚物和(2)固体润滑剂,其包含25-80 PTFE,或15-80%CFx,其中x为0.85-1,或25-80%的混合物。 PTFE和二硫化钼或CFx amt。 (2)的计算基于总重量树脂硬化后在成品中添加树脂和固体润滑剂。用于产品。高速或高温操作的组件滚珠轴承座圈,齿轮,油脂等。预聚物作为制备物。通过在150-250摄氏度下加热cpd。式(I)与二胺H 2 N-B-NH 2(II)的通式(I)(其中D为二价gp,包含CC双键,A为> = 2 C二价gp)的通式(I) 30C二价gp。)。 (I)是首选。 N,N′-4,4′-二苯基甲烷双马来酰亚胺,(II)为优选。双(4-氨基苯基)甲烷。润滑剂优选。占30-50 wt。 %PTFE或15-30%CFx,或28-32%PTFE和3-6%MoS2。

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