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granular activated carbon and method of preparation from coal quality bitumieux less attack by a dilute acid mineral
granular activated carbon and method of preparation from coal quality bitumieux less attack by a dilute acid mineral
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机译:粒状活性炭及由煤质沥青制备的方法,减少了稀酸矿物的侵蚀
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摘要
Granular activated carbon is manufactured from low rank agglomerating but not good coking bituminous coal by crushing and screening the as received coal to produce 8/30 mesh granules, which are treated with a dilute aqueous solution of inorganic acid to prevent fusion of the granules during subsequent devolatilization comprising: mixing the granules with the acid (H2SO4, H3PO4, HCl or mixtures thereof) at a concentration of about 1% to about 15% by weight, washing off the acid, drying the granules thoroughly and thereafter mixing the granules with about 5 to about 15% by weight of a carbonaceous binder such as coal tar pitch. The so treated granules are ground to at least about 65% by weight -325 mesh powder, which is compressed into shapes such as pellets of 0.5 inch diameter and 0.5 inch long under a pressure of 40,000 to 80,000 psi, and then granulated to obtain 6/20 mesh granules. These granules are first charred by heating to 250 DEG C at 150 DEG C/hour in an atmosphere of air and nitrogen and by maintaining the temperature for 4 hours, next devolatilized by heating to 450 DEG C at 300 DEG C/hour in an atmosphere of N2 and the volatiles and by maintaining the temperature for 1 hour, and then activated by heating to 800 DEG to 900 DEG C in an atmosphere of N2 and steam and by maintaining the temperature for 4 to 5 hours. The activated granules have a surface area of 1050 to 1090 m2/gram, an Iodine number of 900 to 1100, an ash content of 6 to 9%, an abrasion number 75 to 80, and an apparent density of 0.51 to 0.53 gram/cc, which properties make them suitable for use in water and waste water treatment and in other applications.
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机译:粒状活性炭是由低级聚结但焦化效果不佳的烟煤制成的,方法是将原煤破碎并过筛,以生产8/30目颗粒,然后用稀无机酸水溶液处理,以防止颗粒在随后的熔化过程中熔化。脱挥发分包括:将颗粒与浓度为约1%至约15%重量的酸(H2SO4,H3PO4,HCl或它们的混合物)混合,洗去酸,彻底干燥颗粒,然后将颗粒与约5至约15重量%的碳质粘合剂例如煤焦油沥青。将如此处理的颗粒研磨成至少约65%重量的-325目粉末,将其在40,000至80,000 psi的压力下压缩成诸如0.5英寸直径和0.5英寸长的粒料的形状,然后造粒以获得6。 / 20目颗粒。这些颗粒首先通过在空气和氮气气氛中以150℃/小时加热至250℃并保持该温度4小时而被烧焦,然后通过在大气中以300℃/小时加热至450℃而挥发掉。 N 2和挥发物并通过保持温度1小时,然后通过在N 2和蒸汽的气氛中加热到800℃至900℃并保持温度4-5小时而活化。活化的颗粒的表面积为1050至1090平方米/克,碘值为900至1100,灰分为6至9%,磨耗值为75至80,表观密度为0.51至0.53克/立方厘米的特性使它们适合用于水和废水处理以及其他应用。
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