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for light sensitive resistbekledingspreparaat and light sensitive product and method for manufacturing a litho - printing plate.

机译:用于光敏抗蚀剂的制备和光敏产品以及制造平版印刷版的方法。

摘要

A photosensitive resist compsn. comprises a soln. in organic solvent of a mixt. of (a) a polyvinylformal (PVF) which is insoluble in water but soluble in organic solvent, has a formal content of 80-100% (based on PVF) and is prepd. by reacting an aldehyde chosen from formaldehyde, its 19:1 mixt. with acrolein and its 9:1 mixt. with crotonaldehyde, with a water soluble polyvinyl alcohol with a mol wt. 16000-100,000 and hydrolysis degree 80-100%, in a reactn. medium comprising 1,4-dioxane or acetic acid and contg. an inorg. acid catalyst, and (b) an aryl diazide which is soluble in organic solvent and is a photosensitiser and crosslinking agent for the PVF. The compsn. is used for prodn. of lithographic printing plates and printed circuits. It is storage stable and forms dried layers which are thermally stable and which after exposure to light are strongly resistant to solvents (e.g. in printing inks) in the exposed regions. Specifically the dried layer is stable when heated at 121 degrees C for 30 mins.
机译:光敏抗蚀剂组合物。包含一个溶液。在混合物的有机溶剂中。 (a)一种不溶于水但可溶于有机溶剂的聚乙烯醇缩甲醛(PVF),其形式含量为80-100%(基于PVF),并且是制备的。通过使选自甲醛的醛以19:1的混合物进行反应。与丙烯醛及其9:1混合物。与巴豆醛,与摩尔重量的水溶性聚乙烯醇。在反应器中为16000-100,000,水解度为80-100%。包含1,4-二恶烷或乙酸的介质。一个Inorg。 (b)芳基二叠氮化物,其可溶于有机溶剂中,并且是PVF的光敏剂和交联剂。该compsn。用于产品。平版印刷版和印刷电路。它是储存稳定的并形成干燥的层,该干燥的层是热稳定的,并且在暴露于光之后在暴露区域中对溶剂(例如在印刷油墨中)具有很强的抵抗力。特别地,当在121℃下加热30分钟时,干燥的层是稳定的。

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