New benzofuranyl N-methylcarbamates are of formula (I). In the formula, X is O or S; R' is alkyl, alkenyl, alkynyl, cycloalkyl, opt. substd. phenyl or phenylalkyl; R2 is H or CH3; and n is O or 1. (I) are pesticides useful as insecticides, acaricides and nematocides. They are well tolerated by plants, and toxicity towards warm-blooded animals is low. In an example, in a test in which cabbage plants strongly infested with Myzus persicae were sprayed to runoff with a dispersion of the test cpd., a 0.1% dispersion of (I; X=O, n= 0, R'=R2=CH3) gaive 100% kill of the aphid and a 0.01% dispersion gave 70% kill; a 0.1% dispersion of the known cpd. 1-naphthyl N-methylcarbamate gave only 80% kill and a 0.01% dispersion had no effect. Specific cpds. (I) include 2,2-dimethyl-2,3-dihydrobenzofuran-7-yl N-methyl-N-acetoxymethylcarbamate.
展开▼
机译:新的苯并呋喃基N-甲基氨基甲酸酯具有式(I)。式中,X为O或S; R'为烷基,链烯基,炔基,环烷基。取代苯基或苯基烷基; R 2为H或CH 3; n为O或1。(I)是用作杀虫剂,杀螨剂和杀线虫剂的农药。它们被植物很好地耐受,并且对温血动物的毒性低。在一个例子中,在试验中,用试验cpd的分散液将强烈侵染了桃蚜的白菜植株喷洒到径流中,其中0.1%的分散液为(I; X = O,n = 0,R'= R2 = CH 3)杀死100%的蚜虫,0.01%的分散度杀死70%。已知cpd的0.1%分散度。 N-甲基氨基甲酸酯的1-萘基仅杀死80%,0.01%的分散液无效。特定的cpds。 (I)包括2,2-二甲基-2,3-二氢苯并呋喃-7-基N-甲基-N-乙酰氧基甲基氨基甲酸酯。
展开▼