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Polymn of aralkyl ether with phenolic cpd - using mercuric, mercurous, cupric or silver cpd as catalyst
Polymn of aralkyl ether with phenolic cpd - using mercuric, mercurous, cupric or silver cpd as catalyst
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机译:芳烷基醚与酚醛cpd的聚合-使用汞,汞,铜或银cpd作为催化剂
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摘要
Prodn. of a polymer by allowing an aralkyl ether or formula : R1 -((CH2OH a (where R1 is an aromatic hydrocarbon or aromatic hydrocarbon ether radical; R is 6C alkyl and a is between 2 and 3) to react with phenol cpd. in amt. 1.3-25 mols./mol. aralkyl ether, by conducting reaction in presence of CuCl2, CuSO4, HgCl2 HgSO4, Hg2Cl2, Hg2SO4, AgCl, Ag2SO4 or NaHSO4, as catalyst. The polymers obtd. have higher softening pts. than those obtd. from phenol cpds. and conventional catalyst and have little cold flow tendencies.
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