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Asymmetrical hydrazine(s) prepn. - by treating mono:chloramine with a primary or secondary amine and sodium hydroxide
Asymmetrical hydrazine(s) prepn. - by treating mono:chloramine with a primary or secondary amine and sodium hydroxide
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机译:不对称肼的制备-通过用伯胺或仲胺和氢氧化钠处理单氯胺
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摘要
Asymmetrical substd. hydrazines are prepd. by treating excess ammonia in the cold with an alkali metal hypochlorite in a water-immiscible solvent to form monochloramine, and this is treated with excess of a primary or secondary amine in the presence of NaOH. The products, eps. dimethyl hydrazine, or liquid propellants, and plant growth regulators. The process is easy to carry out, gives good yields (e.g. 83%) and gives rise to less toxicity, pollution and explosion problems than conventional methods.
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