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Method for the preparation of complexes of metals of the VIII group of the periodic table and their use as catalysts for transferring hydrogen in a heterogeneous phase
Method for the preparation of complexes of metals of the VIII group of the periodic table and their use as catalysts for transferring hydrogen in a heterogeneous phase
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机译:周期表第group族金属配合物的制备方法及其在多相中转移氢的催化剂的用途
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摘要
A method is disclosed for preparing complexes of metals of the VIII Group of the Periodic Table, useful as hydrogenation catalysts. The method, as a single-step process, comprises reacting a polymeric complex containing V Group elements and VIII Group metal compounds directly with a metal atom which is directly bound to the V group element in the presence of a reducing substance. The reducing substance is selected among alkali metal and alkaline earth metal hydrides, mixed alkaline-III group element hydrides, organic metallic compounds of III Group metals, alkali metal and alkaline earth metal alkyls, Grignard compounds.
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