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A sulphonyl urea-containing softener and water-repellant for textiles containing cellulose and for leather, method for the preparation thereof; the sulphonyl ureas and process for their preparation

机译:用于含纤维素的纺织品和皮革的含磺酰脲的柔软剂和防水剂,其制备方法;磺酰脲及其制备方法

摘要

The softening and waterproofing agents for cellulose, cellulose-containing textiles and for leather consist of a part by weight of a compound RB -? - NH-SO2-X (1) in which R is alkyl or alkenyl with 10 to 30 C atoms, B is one of the divalent radicals IMAGE X is β-haloalkyl or alkenyl each having 2 to 4 carbon atoms and R¹ and R² are hydrogen or alkyl having 1 to 4 carbon atoms and n is 2, 3 or 4, and b parts by weight of an emulsifier consisting of 100-37.5% of known nonionic emulsifiers, 0-50% of known anionic emulsifiers and 0 to 25% of known lickers, c parts by weight of an epoxide IMAGE in which R³ is alkyl or alkenyl with 15 to 40 C atoms, and optionally d parts by weight Water or a water-miscible organic solvent, where a has a value from 80 to 99, b has a value from 20 to 1, c has a value from 0 to 5 and IMAGE has a value from 10 to 40. Sulfonylureas of the general formula RB -? - NH-SO2-X in which R is alkyl or alkenyl having 10 to 30 C atoms, B is one of the divalent radicals IMAGE X is β-haloalkyl or alkenyl each having 2 to C atoms and R¹ for alkyl with 1 to 4 carbon atoms, R² for hydrogen or alkyl with 1 to 4 carbon atoms and n for 2, 3 or 4, prepared by reacting a β-haloalkylsulfonyl isocyanate with 2 to 4 carbon atoms in the Alkyl radical of
机译:用于纤维素,含纤维素的纺织品和皮革的柔软剂和防水剂由重量份的化合物RB-?组成。 -NH-SO 2 -X(1),其中R是具有10至30个碳原子的烷基或烯基,B是二价基团之一。IMAGE X是分别具有2-4个碳原子的R 1-卤代烷基或烯基,R 1和R 2为氢或具有1-4个碳原子的烷基,n为2、3或4,b的乳化剂的重量份为100-37.5%的已知非离子乳化剂,0-50%的已知阴离子乳化剂和0-70%。 25%的已知催油剂,c为环氧化物的重量份,其中R3为具有15至40个C原子的烷基或烯基,可选地为d重量份的水或与水混溶的有机溶剂,其中a为从80到99,b的值为20到1,c的值为0到5,的值为10到40。通式RB-α的磺酰脲类。 -NH-SO 2 -X,其中R为具有10至30个碳原子的烷基或烯基,B为二价基团之一。 X为各自具有2至C个原子的β-卤代烷基或烯基,且R 1为具有1至1个碳原子的烷基。通过使β-卤代烷基磺酰基异氰酸酯与2-4个碳原子在烷基的烷基中反应制得的碳原子数为4个,R 2为氢或具有1-4个碳原子的烷基,n为2、3或4。

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