首页> 外国专利> Process for the preparation of 2,2'-methylene- or 2,2'-ethylidinebis(4,6-dialkylphenols) or of 2,2'-methylenebis(4-methyl-6-cyclohexylphenol).

Process for the preparation of 2,2'-methylene- or 2,2'-ethylidinebis(4,6-dialkylphenols) or of 2,2'-methylenebis(4-methyl-6-cyclohexylphenol).

机译:制备2,2'-亚甲基-或2,2'-乙撑双(4,6-二烷基酚)或2,2'-亚甲基双(4-甲基-6-环己基酚)的方法。

摘要

2,2'-methylene- or 2,2'-ethylidinebis(4,6-dialkylphenols) or 2,2'-methylenebis(4-methyl-6-cyclohexylphenol) are obtained by reacting 2,4-dialkylphenols or 4-methyl-2-cyclohexylphenol, respectively, with a condensing agent in the presence of an acid-containing catalyst at a temperature of 30-140 DEG C. Suitable acetals are used as condensing agents. 1 mol of suitable phenol is employed per 1-10 mols of acetal. The acetal simultaneously acts as the diluent. The desired product is isolated from the reaction mixture. The compounds prepared can be used as stabilisers for polymer materials.
机译:通过使2,4-二烷基苯酚或4-甲基反应获得2,2'-亚甲基-或2,2'-乙撑双(4,6-二烷基苯酚)或2,2'-亚甲基双(4-甲基-6-环己基苯酚)在含酸催化剂的存在下,在30-140℃的温度下,用缩合剂分别将-2-环己基苯酚用作缩合剂。每1-10摩尔缩醛使用1摩尔合适的苯酚。乙缩醛同时充当稀释剂。从反应混合物中分离出所需产物。所制备的化合物可用作聚合物材料的稳定剂。

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