Process for the preparation of cubic boron nitride from hexagonal boron nitride powder in the absence of catalyst, the said nitride abrasive particles.Emery containing the particles and process of grinding of steel fast with use of said emery

摘要

Cubic boron nitride has been made from powdered hexagonal boron nitride by a process which comprises vacuum firing of the HBN and conversion by high pressure-high temperature processing at 55-80 kilobars and 1600 DEG C. to the reconversion temperature. The high pressure reaction cell has a special design which prevents the entrance of impurities into the sample. This cell, referring to FIG. 2, comprises, for example, a carbon tube (8) enclosing concentric titanium sleeve (9). Within the cylinder defined by the tube and sleeve are: the HBN sample (4), carbon filler (3), shielding tantalum foil discs (2) and carbon end plugs (10). The vacuum firing is done at pressures of 10-5-10-10 mm Hg, 1400 DEG -1900 DEG C., for 5 minutes-4 hours, and is believed to form a thin, free-boron coating on the HBN particles. The process works on both pyrolytic (turbostratic) and graphitic hexagonal boron nitride. Grinding grits formed by milling cubic boron nitride chunks recovered from the high pressure-high temperature process have resulted in higher grinding ratios than commercially available CBN.