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FREEZING FOR POLYETHY WITH POLYETHYLES AND ENCLOSURES OEVER 500 000
FREEZING FOR POLYETHY WITH POLYETHYLES AND ENCLOSURES OEVER 500 000
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机译:用聚乙烯冻结聚乙烯,并封闭超过50万个外壳
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1451292 Polyethylene production using Ziegler catalyst RUHRCHEMIE AG 9 Dec 1974 [11 Dec 1973] 53141/74 Heading C3P Polyethylene having a molecular weight above 500,000 is obtained by polymerizing ethylene at 30‹ to 130‹ C. in the presence of a Ziegler catalyst comprising (A) a titanium III halide, (B) an organoaluminium compound and (C) an alcohol, the molar raio of (A) to (B) being between 5 : 1 and 1 : 5, the proportion of (C) being 2 to 10 moles per kg. of (A) + (B), and the ethylene monomer containing less than 5 p.p.m. oxygen. Component (C) may be mono- or polyhydric alcohol. The examples refer to batch or continuous ethylene polymerization using a suitably pure monomer, a purified hydrocarbon fraction as diluent, and a catalyst comprising (A) TiCl 3 obtained from TiCl 4 + Et 2 AlCl, (B) Et 2 AlCl and (C) butanol. The minimal oxygen content in the monomer feed ensures that films and deposits on the polymerization vessels and stirrers are largely eliminated.
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机译:1451292使用Ziegler催化剂生产聚乙烯RUHRCHEMIE AG 1974年12月9日[1973年12月11日]标题C3P分子量大于500,000的聚乙烯是通过在Ziegler催化剂的存在下在30℃至130℃聚合乙烯而得到的,该催化剂包括( A)卤化钛III,(B)有机铝化合物和(C)醇,(A)至(B)的摩尔比为5:1至1:5,(C)的比例为2至每公斤10摩尔。 (A)+(B)的化合物,且乙烯单体的含量小于5p.p.m。氧。组分(C)可以是一元或多元醇。实施例涉及使用适当纯的单体,纯化的烃馏分作为稀释剂和包含(A)由TiCl 4 + Et 2 AlCl,(B)Et 2 AlCl和(C)获得的催化剂的间歇或连续乙烯聚合。丁醇。单体进料中的最小氧含量确保了在聚合容器和搅拌器上的薄膜和沉积物被大大消除。
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