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Aqueous copolyester dispersions suited for the subbing of polyester film, subbed polyester film and photographic materials containing a subbed polyester base

机译:水性共聚酯分散体,适用于对聚酯胶片,带底涂层的聚酯胶片和含有带底涂层的聚酯基料的照相材料进行胶粘

摘要

An aqueous copolyester dispersion suitable for the subbing of polyesterfilm without the use of solvents, is characterized in that the copolyester essentially consists of recurring ester groups derived from ethylene glycol and a mixture of terephthalic acid, isophthalic acid and sulphoisophthalic acid whose sulpho group is in salt form, the said acid mixture containing from 20 to 60 mole %of isophthalic acid and from 6 to 10 mole % of said sulphoisophthalic acid, the remainder being terephthalic acid, the copolyester having a glass transition temperature above 45°C and an intrinsic viscosity of from 0.15 to 0.45 dl/g when measured at 25°C in a mixture of phenol/o-dichlorobenzene (60/40 by volume). The sulpho- salt group of the sulphoisophthalic acid may be an alkali metal or onium salt. The aqueous dispersion may be coated onto the polyester film before longitudinal stretching thereof.
机译:一种适合在不使用溶剂的情况下将聚酯膜胶合的水性共聚酯分散液,其特征在于,共聚酯基本上由衍生自乙二醇的重复酯基和对苯二甲酸,间苯二甲酸和磺基间苯二甲酸的混合物组成,其磺基在盐中所述酸混合物包含20至60摩尔%间苯二甲酸和6至10摩尔%磺基间苯二甲酸,其余为对苯二甲酸,共聚酯的玻璃化转变温度高于45°C,特性粘度为当在25℃下在苯酚/邻二氯苯的混合物中(体积比为60/40)测量时为0.15至0.45dl / g。磺基间苯二甲酸的磺酸盐基团可以是碱金属盐或鎓盐。可以在纵向拉伸之前将水分散体涂覆到聚酯膜上。

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