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Processing aqueous effluent liquors from degasification or gasification of coal

机译:煤炭脱气或气化处理水性废水

摘要

The aqueous effluent liquors from gasification or de- gasification of coal are extracted with a water-insoluble solvent and the extract is processed to recover the solvent. The aqueous residue is treated to remove NH.sub.3 in a driving-off column. The invention adds the steps ofPP(a) removing part of the overhead product of the driving-off column as uncondensed vapors;PP(b) transferring the vapors from (a) to a scrubbing column, in steps condensing water, small amounts of ammonia and all acid gases in the upper part of said scrubbing column, and withdrawing pure ammonia overhead;PP(c) withdrawing the condensate which contains all acid gases from the upper portion of the scrubbing column, transferring the condensate to a separate reboiler, and heating the transferred condensate in said reboiler;PP(d) feeding cold water at a low rate to the top of the scrubbing column;P P(e) withdrawing the sump product of the scrubbing column, transferring it into a pressurized de-acidification column, and withdrawing therefrom overhead under pressure the acid gases H.sub.2 S and CO.sub.2 ; andPP(f) recycling to the stripping column the sump product of the pressurized de-acidification column consisting of a solution high in ammonia content.
机译:用不溶于水的溶剂萃取来自煤炭气化或脱气的含水废水液,并对萃取液进行处理以回收溶剂。在排出塔中处理含水残余物以除去NH 3。本发明增加了以下步骤:(P)

(a)除去部分汽提塔的塔顶产物作为未冷凝的蒸气;

(b)将蒸气从(a)转移至洗涤塔,分步冷凝所述洗涤塔上部中的水,少量氨和所有酸性气体,并从塔顶抽出纯氨;(P)(c)从上部抽出含有所有酸性气体的冷凝液洗涤塔的一部分,将冷凝水转移到单独的再沸器中,并在所述再沸器中加热转移的冷凝水;

(d)以低速将冷水供入洗涤塔的顶部;

(e)抽出洗涤塔的集液产物,将其转移到加压的脱酸塔中,并在压力下从塔顶馏出酸性气体H 2 S和CO 2; (f)将加压的脱酸塔的集液产物再循环到汽提塔,该塔的产物由氨含量高的溶液组成。

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