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Process for recovering metals from catalysts for the hydrodesulfurization of hydrocarbons

机译:从催化剂中回收金属以进行烃加氢脱硫的方法

摘要

P the present invention relates to the recovery of the molybdenum, vanadium, aluminium, as well as of the cobalt and nickel from statement of the catalysts of hydrodesulphurization. / p & & p & according to the invention, the residue of hydrodesulphurization catalysts for hydrocarbon has a chlorination by means of a mixture of gaseous chlorine, hydrochloric acid and water vapor, under conditions such that the molybdenum and vanadium are volatilized in the form of oxychlorides and the aluminum in the form of chloride and it absorbs the products thus volatilized by means of an aqueous medium containing hydrochloric acid. The water vapor content of the gaseous mixture of chlorination exceeds does not, then, approximately 15 by volume relative to the total gas mixture. / p
机译:本发明涉及从加氢脱硫催化剂的说明中回收钼,钒,铝以及钴和镍。 & &根据本发明,用于烃的加氢脱硫催化剂的残余物通过气态氯,盐酸和水蒸气的混合物进行氯化,其条件是钼和钒以氯氧化物的形式挥发,而铝以铝的形式挥发。形式的氯化物,它吸收含有盐酸的水介质挥发的产物。氯化气态混合物的水蒸气含量相对于总气体混合物不超过体积的15%。

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