NOVEL HIGHHMOLECULAR COMPOUND HAVING PHASE TRANSFER CATALYTIC EFFECT AND PREPARATION THEREOF

摘要

PURPOSE:To efficiently obtain a high-molecular compound having phase transfer catalystic effect useful as a chemical reaction catalyst, by polymerizing one kind of a monomer such as a vinylphenoxy derivative in the presence of a radical-polymerization initiator or a cationic polymerization initiator. CONSTITUTION:One kind of a monomer ahown by formula I (wherein R is aromatic cyclic group; m is 0-1; n is an integer 1), such as 2-phenoxyethyl vinyl ether or 1-(4-vinylphenoxy)-2-phenoxyethane, is polymerized in the presence of a radical- polymerization initiator such as benzoyl peroxide or a cationic polymerization catalyst such as tin chloride or aluminum chloride to obtain a titled high- molecular compound comprising a polymer consisting of monomer units shown by formula II (wherein R, m, n have the same meaning as defined above).