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Process for the solubilization of organic or mineral salts in organic solvents and complexes of organic or mineral salts

机译:在有机溶剂中溶解有机或无机盐的方法以及有机或无机盐的配合物

摘要

The invention provides a process for solubilizing an organic or mineral salt in an organic solvent, said process comprising contacting an organic or mineral salt of the formula A-M+, wherein A- represents a mineral or organic anion and M+ represents a cation selected from the group consisting of the cation NH4+ and its derivatives and the cations derived from the metals of the groups IA, IIA, IIIA, IVA, VA, VIA, VIIA, VIII, IB, IIB, IIIB, IVB and VB of the periodic table, with at least one sequestering agent which is soluble in said organic solvent, said sequestering agent having the formula: N[CHR1-CHR2-O-(CHR3-CHR4-O)n-R5]3 (I) wherein n is an integer from 0 to 10 inclusive; R1, R2, R3 and R4, which can be the same or different, are each a hydrogen atom or an alkyl radical having 1 to 4 carbon atoms; R5 is an alkyl radical having 1 to 12 carbon atoms, a cycloalkyl radical having 3 to 12 carbon atoms, a phenyl radical, a radical of the formula IMAGE or a radical of the formula IMAGE and m is an integer from 1 to 12 inclusive. The process makes it possible to utilize the A-M+ salt as a reactant in solvents in which such reaction has not heretofore been possible, or to extract the A31 M+ salt from a solution containing it.
机译:本发明提供了在有机溶剂中增溶有机或无机盐的方法,所述方法包括使式A-M +的有机或无机盐接触,其中A-代表无机或有机阴离子,M +代表选自下式的阳离子。包括NH4 +阳离子及其衍生物和周期表中IA,IIA,IIIA,IVA,VA,VIA,VIIA,VIII,IB,IIB,IIIB,IVB和VB族金属衍生的阳离子,至少一种可溶于所述有机溶剂的螯合剂,所述螯合剂具有下式:N [CHR1-CHR2-O-(CHR3-CHR4-O)n-R5] 3(I)其中n为0以下的整数至10(含); R 1,R 2,R 3和R 4可以相同或不同,分别为氢原子或具有1-4个碳原子的烷基。 R 5是具有1至12个碳原子的烷基,具有3至12个碳原子的环烷基,苯基,式的基团或式的基团,并且m是1以上的整数。至12点(含)。该方法使得可以在迄今不可能进行该反应的溶剂中利用A-M +盐作为反应物,或者从包含它的溶液中提取A31M +盐。

著录项

  • 公开/公告号EP0016673B1

    专利类型

  • 公开/公告日1982-02-10

    原文格式PDF

  • 申请/专利权人 RHONE-POULENC SPECIALITES CHIMIQUES;

    申请/专利号EP19800400250

  • 发明设计人 SOULA GERARD;

    申请日1980-02-22

  • 分类号C07C93/04;

  • 国家 EP

  • 入库时间 2022-08-22 13:09:27

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