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Quaternized, bridged benzimidazolylbenzimidazoles, processes for their preparation and their use

机译:季铵化桥联苯并咪唑基苯并咪唑,其制备方法和用途

摘要

Compounds of the general formula (1) ##STR1## wherein R.sub.1 denotes hydrogen, halogen, alkyl, alkoxy or, conjointly with R.sub.2, a fused benzo ring, R.sub.2 denotes hydrogen, alkyl, alkoxy, halogen, phenyl, cyano, carboalkoxy, carboxyl, carbonamido, monoalkylcarbonamido, dialkylcarbonamido, sulfo, alkylsulfonyl, alkyloxysulfonyl, sulfonamido, monoalkylsulfonamido or dialkylsulfonamido or, conjointly with R.sub.3, a fused benzo ring, R.sub. 3 has the same meaning as R.sub.2, R.sub.4 denotes hydrogen, alkyl, alkoxy, halogen or, conjointly with R.sub.3, a fused benzo ring, R.sub.5 denotes alkyl, hydroxyalkyl, alkoxyalkyl, optionally substituted aralkyl, cyanoethyl, cycloalkyl or a group of the formulae --CH.sub.2 CN, --CH.sub.2 CONH.sub. 2 or --CH.sub.2 COO--alkyl, A denotes a group of the formulae ##STR2## or ##EQU1## R.sub.6 denotes hydrogen, alkyl, hydroxyalkyl, alkoxyalkyl, aralkyl or optionally substituted phenyl, n denotes 1, 2 or 3 and X.sup.(-) denotes a halide, alkylsulfonate, alkylsulfate, alkylphenylsulfonate or phenylsulfonate ion, and processes for their preparation and their use as optical brighteners.
机译:通式(1)的化合物其中R 1表示氢,卤素,烷基,烷氧基,或者与R 2一起稠合的苯并环,R 2表示氢,烷基,烷氧基,卤素,苯基,氰基,碳烷氧基,羧基,碳酰胺基,单烷基碳酰胺基,二烷基碳酰胺基,磺基,烷基磺酰基,烷基氧基磺酰基,磺酰胺基,单烷基磺酰胺基或二烷基磺酰胺基,或与R 3结合的稠合苯并环。 3与R 2的含义相同,R 4表示氢,烷基,烷氧基,卤素,或与R 3一起稠合的苯并环,R 5表示烷基,羟烷基,烷氧基烷基,任选取代的芳烷基,氰基乙基,环烷基或式--CH.sub.2 CN,-CH.sub.2 CONH.sub。 2或--CH.sub.2 COO-烷基,A表示式为## STR2 ##或## EQU1 ## R.sub.6表示氢,烷基,羟烷基,烷氧基烷基,芳烷基或任选取代的苯基,n表示1、2或3,X(-)表示卤化物,烷基磺酸根,烷基硫酸根,烷基苯基磺酸根或苯基磺酸根离子,及其制备方法和用作荧光增白剂的用途。

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