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Catalysts preparation process based on molybden and/or tungsten oxides and oxides of other metals

机译:基于钼氧化物和/或钨氧化物和其他金属氧化物的催化剂制备方法

摘要

the invention relates to a preparation process of catalysts comprising an active phase in response to the general formula:ji also aa bb ox;in which:a represents at least one metal selected from the group consisting of cobalt, nickel, manganese, lead, and b is at least one metal selected from the group consisting of iron, bismuth.chromium, thallium - representing the sum of the indices assigned to each of the metals.is greater than 0 and less than or equal to about 12 (c) and (d) are each equal to or greater than 0 and less than or equal to 12.the sum of c + d is equal to approximately 12 '(representing the sum of the indices assigned to each of the metal b is greater than 0 and less than or equal to about 1.(c + d) - (a - x satisfies the process that induces a type, as a first step, the aqueous phase is mixed metal salts used in the composition of the active phase.molybdenum and tungsten in the form of ammonium salts, and at least one of the metals a and b are in the form of a nitrate or chloride, in a second step.dry pulp is obtained, and in a third step, at least a calcination is eventually deposited on the solid support obtained, process, characterized in that in the first stage.successively, is added to a first aqueous solution containing ammonium salts of molybdenum and tungsten in quantity to achieve the values of c and d,a second aqueous solution containing the salt of a and b in a quantity to achieve the values of a and bby adding to the mixture of ammonia until a ph higher than the ph of the aqueous solution of initial and first in the solution to obtain a filterthe paste.
机译:本发明涉及响应于通式包括活性相的催化剂的制备方法:ji也是bb ox;其中:a表示选自钴,镍,锰,铅和b的至少一种金属,b表示选自铁,铋,铬,th的至少一种金属-代表分配给每种元素的指数之和大于0且小于或等于约12的金属(c)和(d)分别等于或大于0且小于或等于12.c + d之和等于约12 '(代表分配给每种金属b的指数之和大于0且小于或等于约1.(c + d)-(a-x满足诱导类型的过程,第一步在第二种方法中,水相是用于活性相组成的混合金属盐。钼和钨以铵盐的形式存在,而金属a和b中的至少一种以硝酸盐或氯化物的形式存在于第二相中。获得干浆,并且在第三步骤中,至少煅烧最终沉积在获得的固体载体上。 d。方法,其特征在于,在第一阶段中,成功地向含有钼和钨的铵盐的第一水溶液中添加一定数量的碳,以达到c和d的值;含有a和b的盐的第二水溶液。加入到氨的混合物中直至达到pH值高于溶液中最初和最先的水溶液的pH值,以获得糊剂的量。

著录项

  • 公开/公告号EP0039267B1

    专利类型

  • 公开/公告日1983-05-25

    原文格式PDF

  • 申请/专利权人 RHONE-POULENC CHIMIE DE BASE;

    申请/专利号EP19810400575

  • 发明设计人 DERRIEN JEAN-YVES;

    申请日1981-04-10

  • 分类号B01J23/24;B01J23/88;

  • 国家 EP

  • 入库时间 2022-08-22 10:33:56

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