A method of identifying potential low water cut hydrocarbon producing zones of a formation having significant water saturation (i.e. about 50% or more of the available pore space). The formation is logged to determine its water saturation. The formation rock is sampled at a level at which the log-indicated water saturation is significant. Sample rock is cleaned of hydrocarbons and saturated with brine. The spin-lattice relaxation time of hydrogen nuclei of the water molecules of the wetted sample is determined using nuclear magnetic resonance techniques and is used to determine the surface area of the sampled rock. An irreducible water saturation of the sampled formation rock is determined from the measured surface area and is plotted with the log-indicated formation water saturation at or at and about the level from which the rock sample was obtained. Levels where the irreducible water saturation approximate or exceed the log-indicated formation water saturation are zones from which hydrocarbons potentially may be recovered without significant attendant water production.
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