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Process for producing acicular ferromagnetic alloy particles and acicular ferromagnetic alloy particles obtained by the said process

机译:制备针状铁磁性合金颗粒的方法和通过所述方法获得的针状铁磁性合金颗粒

摘要

A process for producing an acicular ferromagnetic alloy particles mainly containing iron and magnesium, which comprises preparing a suspension of iron(II) hydroxide and water-soluble magnesium salt, the suspension having a pH value of at least 11 and containing the magnesium salt in an amount of 0. 5 to 20.0 atomic % based on the amount of the iron(II) hydroxide in the suspension and calculated as the ratio of Mg to Fe(II), oxidizing the suspension with an oxygen-containing gas to form an acicular particles of iron(III) oxide hydroxide substituted with magnesium, forming coats of phosphorus compound and subsequent silicon compound on the acicular particles, heating the resultant particle at 500. degree. to 900° C. under a non-reducing atmosphere and then reheating the particle thus treated at 350° to 600° C. under reducing atmosphere.
机译:一种主要包含铁和镁的针状铁磁合金颗粒的制备方法,该方法包括制备氢氧化铁(II)和水溶性镁盐的悬浮液,该悬浮液的pH值至少为11,并且在水中含有镁盐。相对于悬浮液中氢氧化铁(II)的量为0. 5至20.0原子%,并以Mg与Fe(II)的比例计算,用含氧气体氧化悬浮液以形成针状颗粒用镁代替氢氧化铁(III)的氢氧化物,在针状颗粒上形成磷化合物和随后的硅化合物的涂层,将所得颗粒在500℃下加热。在非还原性气氛下加热至900℃,然后在还原性气氛下将如此处理的颗粒在350℃至600℃下再加热。

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