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Liq. oxidn. of pseudo-cumene or durene - to trimellitic or pyromellitic acid using catalyst contg. cobalt, manganese, bromine and opt. zirconium
Liq. oxidn. of pseudo-cumene or durene - to trimellitic or pyromellitic acid using catalyst contg. cobalt, manganese, bromine and opt. zirconium
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机译:酒氧化。续催化剂将准枯烯或硬戊二烯制为偏苯三酸或均苯四酸。钴,锰,溴和opt。锆
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摘要
Oxidn. of pseudocumene (I) or durene (II) by molecular oxygen into trimellitic or pyromellitic acid resp. is effected in liquid phase in presence of a source of Co, a source of Mn plus a source of Br, and opt. a source of Zr, at 100-275 deg.C. The bromine is added in at least 2 steps, 10-35 wt.% of the total bromine being added in the first step and the rest is added in the last step, the temp. in the last step being 175-275 deg.C and that in the preceding step being 125-165 deg.C.
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