首页> 外国专利> FOERFARANDE FOER SAMTIDIG AOTERVINNING AV URAN SAELLSYNTA JORDMETALLER TORIUM OCH YTTRIUM FRAON EN SYRALOESNING

FOERFARANDE FOER SAMTIDIG AOTERVINNING AV URAN SAELLSYNTA JORDMETALLER TORIUM OCH YTTRIUM FRAON EN SYRALOESNING

机译:从酸溶液中当代回收铀释放土壤金属中的钇和钇的方法

摘要

1. A continuous process for the total recovery of uranium IV and/or VI, thorium, yttrium and rare earths contained in an acid aqueous starting phase which is a crude wet-process phosphoric acid or else which was produced either from a residual phosphogypsum containing said metal species in an insoluble state by treatment by means of a strong inorganic acid in aqueous solution, or as an aqueous raffinate from extraction with water-insoluble or weakly water-soluble solvents of a crude wet-process phosphoric acid, characterised in that said acid aqueous solution is brought into contact with a homogenous organic phase comprising a di-(alkylphenyl) phosphoric acid which is free from mono-(alkylphenyl) phosphoric derivative and an inert organic solvent selected from aliphatic or aromatic hydrocarbons used alone or in the form of a mixture, whereby, as the result, after separation of the phases, there are collected a substantially exhausted aqueous phase and an organic phase charged with uranium, thorium, yttrium and rare earths.
机译:1.一种连续工艺,用于完全回收酸性含水起始相中所含的铀IV和/或VI,th,钇和稀土,该起始相为粗制湿法磷酸,或者由残留的含磷石膏制得通过在水溶液中用强无机酸处理或以水不溶性或弱水溶性溶剂萃取粗制湿法磷酸提取的提余液形式的不溶状态的所述金属物质,其特征在于,使酸性水溶液与均质有机相接触,该均质有机相包含不含单-(烷基苯基)磷酸衍生物的二-(烷基苯基)磷酸和选自单独或以下列形式使用的脂族或芳族烃的惰性有机溶剂混合物,因此,在分离各相之后,收集了基本上耗尽的水相和装有尿烷的有机相铝,or,钇和稀土。

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