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Process for producing ethylene glycol and/or glycolic acid ester, catalyst composition used therefor, and process for the production of this composition

机译:乙二醇和/或乙醇酸酯的制备方法,所用的催化剂组合物以及该组合物的制备方法

摘要

A hydrogenation catalyst composition useful for the hydrogenation of an oxalate diester, said composition being composed of a reduction product of copper-containing silica gel formed by contacting an amine complex of copper with colloidal silica sol; and a process for producing the aforesaid composition. Using a catalyst composed of the aforesaid composition, ethylene glycol and/or a glycolic acid ester can be produced from an oxalate diester efficiently with high conversions and selectivities and without causing pollution attributed to the use of a chromium-containing catalyst composition.
机译:一种用于草酸盐二酯氢化的氢化催化剂组合物,所述组合物由通过使铜的胺络合物与胶态硅溶胶接触而形成的含铜硅胶的还原产物组成。以及制备上述组合物的方法。使用由上述组合物组成的催化剂,可以由草酸酯二酯有效地以高转化率和选择性生产乙二酸酯和/或乙醇酸酯,并且不会由于使用含铬催化剂组合物而引起污染。

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