首页> 外国专利> Brief description of the object of the physical properties of the products of paper, paper thus treated, the additive composition had use, the production of paper products, products of the paper obtained and to increase the resistance of the paper in the wet state

Brief description of the object of the physical properties of the products of paper, paper thus treated, the additive composition had use, the production of paper products, products of the paper obtained and to increase the resistance of the paper in the wet state

机译:简要描述纸产品的物理性质的目的,如此处理的纸,已使用的添加剂组合物,纸产品的生产,所获得的纸产品以及增加纸在湿态下的电阻

摘要

The invention relates to a process in order to improve the physical properties of the products of paper. / p & & p & according to the invention, it is possible to prepare an amine salt of the polymer of polyurethane in preparing a cap of the isocyanate prepolymer, which is composed of a mixture of 2,9 is approximately 50% by weight of a polyol cap of isocyanate having a hydroxyl functionality between 3 and 8 before be cap, and about 97,1 is approximately 50 by weight of a polyoxyethylene diol having a hydrophilic cover of the isocyanate of ethylene oxide content of at least 40 mol%, by react this prepolymer with about 0,8 a 1,2 population of a ketoxime chosen from the group consisting of acetone oxime, butanone oxime, cyclohexanone oxime and their mixtures in order to lock the nco groups of the prepolymer in order to form a prepolymer, which blocks the oxime, by react this prepolymer with an amine polyfunctional containing at least two functional groups and capable of forcing the polyurethane to harden at low temperatures, in order to form a reaction product of amine and by react this product with an organic or inorganic acid to form an amine salt of the polymer of polyurethane which hardens at low temperature, and highly miscible in water, it forms a piece of the system of paper, and it is thus intimately the salt in the product of paper, either before or after the formation of the piece, but before the passage of this piece in the stage of drying of the operation of the formation of paper in a quantity sufficient to produce a concentration of the salt of the order of 0,1 to approximately 10 based on the weight of the fibers dry. / p & & p & the invention applies in particular in the papermaking.
机译:本发明涉及一种用于改善纸制品的物理性能的方法。 & &根据本发明,可以在制备异氰酸酯预聚物的封端中制备聚氨酯聚合物的胺盐,该封端由2,9的混合物组成,该混合物是异氰酸酯多元醇封端的约50重量%,其中通过使该预聚物与约0反应,在封端之前3至8之间的羟基官能度,和约97.1重量%是约50重量%的聚氧化乙烯二醇,该亲水性覆盖环氧乙烷的异氰酸酯含量为至少40mol%。 ,8,一种1,2-酮肟,选自丙酮肟,丁酮肟,环己酮肟及其混合物,以便锁定预聚物的nco基团,从而形成可阻断肟的预聚物使该预聚物与包含至少两个官能团的胺多官能团反应,该胺多官能团能够迫使聚氨酯在低温下硬化,从而形成胺的反应产物,并使该产物与氨基甲酸酯反应。有机或无机酸形成聚氨酯聚合物的胺盐,该胺盐在低温下硬化并与水高度混溶,形成纸系统的一部分,因此与纸产品密切相关。在形成纸片之前或之后,但在纸的形成操作的干燥阶段中,在通过该纸片之前,其量足以产生0.1至大约10的盐浓度。基于纤维干重。 & &本发明尤其适用于造纸。

著录项

  • 公开/公告号FR2474553B1

    专利类型

  • 公开/公告日1985-07-19

    原文格式PDF

  • 申请/专利权人 GRACE AND CO;

    申请/专利号FR19810001498

  • 发明设计人

    申请日1981-01-27

  • 分类号D21H3/38;C08L75/08;D21D3/00;

  • 国家 FR

  • 入库时间 2022-08-22 07:56:20

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