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AN IMPROVED PROCESS FOR OXIDIZING AROMATIC COMPOUNDS CONTAINING REACTIVE CARBON-HYDROGEN BONDS

机译:氧化反应性碳氢键合芳烃的改进工艺

摘要

pAn inactivation of the catalytic system easily occurs during the oxidation of reactive aromatics by means of molecular oxygen, in a carboxylic acid solution and in presence of a catalyst which, consists itself of a cobalt compound with optional addition of a manganese compound and a bromine compound, which are appropriate as co-catalyst. This inactivation of the catalytic system may be avoided by the treatment of the catalyst, after each reaction cycle, by means of a strong oxidation agent, reactivating the catalyst; the water produced by the reaction will be eliminated by distillation./p[WO8203625A1]
机译:在分子溶液中,在羧酸溶液中,在催化剂的作用下,反应性芳族化合物的氧化很容易发生催化体系的失活,该催化剂本身由钴化合物组成,并可选地添加锰化合物和溴化合物,适合用作助催化剂。可以通过在每个反应循环之后通过使用强氧化剂再活化催化剂来处理催化剂来避免催化体系的这种失活。反应产生的水将通过蒸馏除去。 [WO8203625A1]

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