Ruthenium-copper-containing, activated-carbon-supported catalyst and process for making alcohol using same

摘要

A catalyst is disclosed which comprises a ruthenium-copper- containing complex of the formula ##EQU1## wherein M is selected from the group consisting of Ce, Cr, Fe, Mn, and mixtures thereof,P PA is an alkali metal, alkaline earth metal or mixture thereof, P Pa is from 0 to about 1,PPb is from about 0. 002 to about 10,PPc is from about 0.2 to about 20, P Pz is from 0 to about 1% by weight,PPx is the number of oxygens needed to fulfill the valence requirements of the other elements, said complex being supported by an activated carbon support having a surface area of at least about 300 square meters per gram. PPA process for converting mixtures of hydrogen and carbon monoxide, particularly synthesis gas, to alcohol with minimal levels of hydrocarbon by-products being formed is also disclosed.