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Recausticizing kraft green liquor

机译:牛皮纸绿液的再造化

摘要

A process of recausticizing kraft green liquor in which the green liquor containing sodium carbonate is passed in a stream in admixture with particles comprising slaked lime, in which stream the liquid phase becomes progressively weaker in sodium carbonate and stronger in sodium hydroxide. Lime is added in order to provide a continuous supply of slaked lime for reaction with the sodium carbonate, and the stream is passed to a solids/liquid separator which recovers liquid phase from said stream, strong in NaOH, continuously and separately from the solid phase of the stream, as white liquor. The rate of the recausticizing reaction is limited by the rate of diffusion of carbonate ion into the solid particles, and of hydroxyl ion out of the solid particles. Typically, these rates limit the amount of causticizing achieved to less than the equilibrium value. In order to overcome this diffusion limitation, more reaction time for partially reacted lime particles is provided by increasing the time for which solids are detained in the system, e.g. by recycling solids. The recycling can be conducted in a system employing co- current flow of the solids and liquids, or, advantageously, counter- current flow.
机译:使牛皮纸生液再塑化的方法,其中使含碳酸钠的生液与包含熟石灰的颗粒混合流过,其中液相在碳酸钠中逐渐变弱而在氢氧化钠中变强。加入石灰是为了提供与石灰酸钠反应的熟石灰连续供应,并且将料流通入固/液分离器,该分离器从所述料流中回收浓的NaOH溶液,连续地且与固相分离。溪流,为白酒。所述重塑化反应的速度受到碳酸根离子向固体颗粒中的扩散和氢氧根离子从固体颗粒中的扩散的速度的限制。通常,这些速率将所实现的苛化量限制为小于平衡值。为了克服该扩散限制,通过增加将固体保留在系统中的时间,例如通过增加反应时间,为部分反应的石灰颗粒提供了更多的反应时间。通过回收固体。再循环可以在采用固体和液体并流,或有利地采用逆流的​​系统中进行。

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