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Alkylidene bisphenol phosphites and phosphates having 2,2,6,6- tetramethyl piperidinyl groups and synthetic resin composition

机译:具有2,2,6,6-四甲基哌啶基的亚烷基双酚亚磷酸酯和磷酸酯以及合成树脂组合物

摘要

Alkylidene bisphenol phosphites and phosphates having 2,2,6,6- tetramethyl piperidinyl groups are provided having the formula: ##STR1## wherein: R.sub.1 is alkyl having from one to about twelve carbon atoms; PPR.sub.2, R.sub.3 and R.sub.4 are each selected from the group consisting of hydrogen and alkyl having from one to about twelve carbon atoms;PPm is 0 or 1;PPn is 0 or 1; PPX is selected from the group consisting of ##STR2## wherein: R.sub.5 is selected from the group consisting of hydrogen, oxyl O.sup.2, alkyl having from one to about twelve carbon atoms; arylalkyl having from seven to about eighteen carbon atoms; 2,3-epoxypropyl, acyl having from one to about eight carbon atoms and ##STR3## in which R.sub.6 is selected from the group consisting of hydrogen, alkyl having from one to about twelve carbon atoms and phenyl, and Y.sub.1 is selected from the group consisting of hydrogen; acyl having from one to about twelve carbon atoms; and ##STR4## Z.sub.1 is selected from the group consisting of ##STR5## wherein R.sub.7 is alkyl from one to about twelve carbon atoms; and ##STR6## wherein: R.sub.6 is selected from the group consisting of hydrogen, alkyl having from one to about twelve carbon atoms and phenyl; andPPZ.sub.2 is selected from the group consisting of ##STR7## in which R.sub.7 is alkyl having from one to about twelve carbon atoms; R.sub.6 is alkylene having from one to about eight carbon atoms andPPY.sub.2 is selected from the group consisting of hydrogen and acyl having from one to about eight carbon atoms.
机译:提供具有2,2,6,6-四甲基哌啶基的亚烷基双酚亚磷酸酯和磷酸酯,其具有下式:其中R1是具有1至约12个碳原子的烷基;

R.sub.2,R.sub.3和R.sub.4各自选自氢和具有1至约12个碳原子的烷基;为0或1;

n为0或1;

X选自由下列组成的组:其中R 5选自氢,氧基O 2,具有1至约十二个碳的烷基原子具有7至约18个碳原子的芳基烷基; 2,3-环氧丙基,具有一个至约八个碳原子的酰基和其中R 6选自氢,具有一个至约十二个碳原子的烷基和苯基,以及Y.sub.1选自氢;具有1至约十二个碳原子的酰基;和## STR4 ## Z.sub.1选自由## STR5 ##组成的组,其中R.sub.7是从一个到大约十二个碳原子的烷基;其中R 6选自氢,具有1至约12个碳原子的烷基和苯基;和P 2 Z 2选自其中R 7为具有1至约12个碳原子的烷基;和R 6是具有一个至大约八个碳原子的亚烷基,并且P 2选自选自氢和具有一个至大约八个碳原子的酰基。

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