首页> 外国专利> LAMINATE STRUCTURE COMPRISING CRYSTALLINE PROPYLENE RESIN SUBSTRATE AND CRYSTALLINE PROPYLENE POLYMER HEAT SEALABLE LAYER; CRYSTALLINE PROPYLENE POLYMER COMPOSITION

LAMINATE STRUCTURE COMPRISING CRYSTALLINE PROPYLENE RESIN SUBSTRATE AND CRYSTALLINE PROPYLENE POLYMER HEAT SEALABLE LAYER; CRYSTALLINE PROPYLENE POLYMER COMPOSITION

机译:包含丙烯酸丙烯树脂基体和丙烯酸丙烯聚合物热封层的层状结构;结晶丙烯聚合物组合物

摘要

A laminated structure comprising a substrate layer of a crystalline propylene resin and, positioned in direct contact with at least one surface of said substrate layer, a heat-sealable layer of a crystalline random propylene copolymer composition, wherein the crystalline random propylene copolymer composition is a mixture composed of (I) a crystalline random propylene copolymer of a major amount of propylene with a minor amount of another alpha-olefin, and (II) a random copolymer consisting essentially of more than 60 to 99 mole % of 1-butene and less than 40 to 1 mole % of propylene, the weight ratio of (I)/(II) being from 5/95 to 90/10, and the radom copolymer (II) has (A) an intrinsic viscosity [ eta ], determined in decalin at 135 DEG C., of 0.5 to 6 dl/g, (B) a DSC melting point (Tm), measured by a differential scanning calorimeter, of 50 to 130 DEG C., (C) a degree of crystallinity, measured by X-ray diffractometry, of 5 to 60%, (D) a boiling methyl acetate-soluble content (W1) of not more than 2% by weight based on the weight of the copolymer (II), and (E) an n-decane/acetone (1:1 by volume) mixture-soluble content (W2) of less than 4x[ eta ]-1.2 in % by weight based on the weight of the copolymer (II); and a crystalline random propylene copolymer composition used for the said laminated structure.
机译:一种层压结构,其包含结晶丙烯树脂的基底层,并且定位成与所述基底层的至少一个表面直接接触,是结晶无规丙烯共聚物组合物的可热封层,其中所述结晶无规丙烯共聚物组合物是由(I)大量丙烯与少量其他α-烯烃组成的结晶无规丙烯共聚物和(II)基本由60至99摩尔%以上的1-丁烯组成的无规共聚物组成的混合物(I)/(II)的重量比为5/95至90/10,丙烯为40〜1摩尔%,且无规共聚物(II)具有(A)特性粘度[η]。 135℃的萘烷为0.5至6dl / g,(B)通过差示扫描量热计测得的DSC熔点(Tm)为50至130℃,(C)为结晶度。通过X射线衍射法测得为5至60%,(D)沸腾的乙酸甲酯可溶物(W1)相对于共聚物(II)和(E)的重量,不超过2重量%,正癸烷/丙酮(体积比为1:1)混合物可溶物含量(W2)小于4x [eta] -1.2重量%,基于共聚物(II)的重量;以及用于上述层叠结构的结晶性无规丙烯共聚物组合物。

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