Graphite or glassy carbon electrode with modified surface

摘要

An electrode has a graphite or glassy carbon surface at least part of which is an edge-plane graphite surface or glassy carbon surface to which Cr(III) complexes are attached by surface C-0 groups. The graphite can be polished pyrolytic graphite. The complex coverage can be 5-20%. The complex may comprise proteins, enzyme substrates, specific binding agents, intermediate metabolites or the like, e.g. the protein plastocyanin, so that direct unmediated electrochemistry is possible at the electrode.